Furnishing Amine-Functionalized Metal-Organic Frameworks with the beta-Amidoketone Group by Postsynthetic Modification
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Cadman, Laura K
Hamzah, Harina Amer
Mahon, Mary F
Raithby, Paul R
Burrows, Andrew D
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Abstract
© 2016 American Chemical Society. Postsynthetic modification (PSM) of amino-functionalized metal-organic frameworks (MOFs) to those bearing pendant β-amidoketone arms using diketene is herein reported. Three unique MOF families demonstrate the scope of this transformation, which both is atom-economical and yields high conversions. In each case, the crystallinity was retained, and instances of exceptional solid-state ordering were observed in the PSM products, which has allowed detailed crystallographic characterization in multiple instances.
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Inorganic Chemistry
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55
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21
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This document is the Postprint of a Published Work that appeared in final form in Inorganic Chemistry, copyright 2016 American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.inorgchem.6b01917
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Inorganic chemistry
Physical chemistry
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Chemistry, Inorganic & Nuclear
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Gee, WJ; Cadman, LK; Hamzah, HA; Mahon, MF; Raithby, PR; Burrows, AD, Furnishing Amine-Functionalized Metal-Organic Frameworks with the beta-Amidoketone Group by Postsynthetic Modification, Inorganic Chemistry, 2016, 55 (21), pp. 10839-10842