Crystal structure of bis(NN-diethyldithiocarbamato)mercury(II)

No Thumbnail Available
File version
Author(s)
HEALY, PC
WHITE, AH
Griffith University Author(s)
Primary Supervisor
Other Supervisors
Editor(s)
Date
1973
Size
File type(s)
Location
License
Abstract

The crystal structure of the title compound, has been determined by single crystalX-ray diffraction by conventional heavy-atom methods. The structure was refined by block-diagonal least-squares procedures to a final R of 0籲 for 810 visually estimated reflections. Crystals are monoclinic, P21/a, a= 11縶1 (8), b= 15簲(1), c= 4緵1 (4)Ŭ = 106糰(6)ଠZ= 2. The centrosymmetric mercury atoms have three pairs of sulphur contacts in a highly distorted array, one pair close [Hg-S 2糹7(6)ŝ, and the others arising out of a sharing of the second sulphur between adjacent mercury atoms [Hg-S 2繹0(7), Hg-S 3糰7(7)ŝ yielding a helical quasi-polymeric array. The asymmetric co-ordination of the ligand is reflected in associated distortion of the CS2 geometry [C-S, 1綹(2) 1緶(2)Ŭ S-C-S 120(1)ݮ The remainder of the ligand geometry is normal.

Journal Title

Journal of the Chemical Society : Dalton Transactions : Inorganic Chemistry

Conference Title
Book Title
Edition
Volume

1973

Issue

3

Thesis Type
Degree Program
School
Patent number
Funder(s)
Grant identifier(s)
Rights Statement
Rights Statement

© 1973 Royal Society of Chemistry. Please refer to the journal link for access to the definitive, published version.

Item Access Status
Note
Access the data
Related item(s)
Subject
Persistent link to this record
Citation
Collections