Electron-impact excitation of the (5d106s)2S1/2→(5d106p)2P1/2,3/2 resonance transitions in gold atoms

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Maslov, M
Brunger, MJ
Teubner, PJO
Zatsarinny, O
Bartschat, K
Fursa, D
Bray, I
McEachran, RP
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2008
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Abstract

Results from a joint experimental and theoretical investigation of electron-impact excitation of the (5 d10 6s) S2 1/2 → (5 d10 6p) P2 1/2,3/2 resonance transitions in gold atoms are presented. The calculations were performed using three fully relativistic approaches, namely, a distorted-wave ansatz, a convergent close-coupling method, and a B -spline R -matrix method. The experimental data are independently normalized to the Bethe-Born formula using the currently preferred experimental values of the optical oscillator strengths. There is generally good agreement between the measured and predicted energy dependences of the integral cross section, provided that sufficient care is taken in the theoretical structure models to ensure that the proper optical oscillator strengths for the two transitions are obtained. A strong resonance feature seen only in the near-threshold excitation of the (5 d10 6p) P2 1/2 state is classified as a (5 d10 6 p2) D1 2 temporary state of the negative gold ion. © 2008 The American Physical Society.

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Physical Review A

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77

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6

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© 2020 American Physical Society. This is the author-manuscript version of this paper. Reproduced in accordance with the copyright policy of the publisher. Please refer to the journal's website for access to the definitive, published version.

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Mathematical sciences

Physical sciences

Chemical sciences

Science & Technology

Optics

Physics, Atomic, Molecular & Chemical

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Maslov, M; Brunger, MJ; Teubner, PJO; Zatsarinny, O; Bartschat, K; Fursa, D; Bray, I; McEachran, RP, Electron-impact excitation of the (5d106s)2S1/2→(5d106p)2P1/2,3/2 resonance transitions in gold atoms, Physical Review A, 2008, 77 (6), pp. 062711

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