A dianionic 5-sufonatosalicylate species in the proton-transfer compound bis(benzylaminium) 3-carobxylato-4-hydroxybenzenesulfonate
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Wermuth, UD
Healy, PC
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John R. Helliwell
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Abstract
The crystal structure of anhydrous bis(benzylaminium) 5-sulfonatosalicylate, 2C7H10N+烷H4O6S2-, from the reaction of benzylamine with 5-sulfosalicylic acid, shows the presence of a dianionic 5-sulfonatosalicylate species, uncommon among proton-transfer compounds of this acid with organic Lewis bases. Hydrogen-bonding interactions between both aminium N+-H groups of the two cations and both the sulfonate and carboxylate O-atom acceptors of the anions give a layered two-dimensional network structure.
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Acta crystallographica. Section E, Structure reports online
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62
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5
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© The Author(s) 2006. For information about this journal please refer to the journal's website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See http://creativecommons.org/licenses/by/2.0/uk/legalcode
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Chemical Sciences