There is little question that the “electronic revolution” of the 20th century has impacted almost every aspect of human life. However, the emergence of solid‐state electronics as a ubiquitous feature of an advanced modern society is posing new challenges such as the management of electronic waste (e‐waste) that will remain through the 21st century. In addition to developing strategies to manage such e‐waste, further challenges can be identified concerning the conservation and recycling of scarce elements, reducing the use of toxic materials and solvents in electronics processing, and lowering energy usage during fabrication methods. In response to these issues, the construction of electronic devices from renewable or biodegradable materials that decompose to harmless by‐products is becoming a topic of great interest. Such “green” electronic devices need to be fabricated on industrial scale through low‐energy and low‐cost methods that involve low/non‐toxic functional materials or solvents. This review highlights recent advances in the development of biodegradable materials and processing strategies for electronics with an emphasis on areas where green electronic devices show the greatest promise, including solar cells, organic field‐effect transistors, light‐emitting diodes, and other electronic devices.