tert-Butyl 2-(3-acetylamino-2-oxo-1,2-dihydro-1-pyridyl)acetate

Loading...
Thumbnail Image
File version
Author(s)
Karis, N David
Loughlin, Wendy A
Jenkins, Ian D
Healy, Peter C
Primary Supervisor
Other Supervisors
Editor(s)
John R. Helliwell
Date
2008
Size
324471 bytes
File type(s)
application/pdf
Location
License
http://creativecommons.org/licenses/by/2.0/uk/legalcode
Abstract

The title compound, C13H18N2O4, crystallizes as discrete molecules associated as N-H...O hydrogen-bonded dimers disposed about a crystallographic inversion centre. The structure is the first solid-state structure for a 3-acetylpyridone without C-4 to C-6 substituents. The amide subsituent at C-3 is coplanar with the pyridone ring, while the tert-butyl ester group is orthogonal to the pyridine ring. The amide and ester carbonyl O atoms are not involved in strong hydrogen bonding with only a number of intramolecular and intermolecular C-H...O interactions apparent in the structure.

Journal Title
Acta Crystallographica. Section E, Structure reports online
Conference Title
Book Title
Edition
Volume
64
Issue
12
Thesis Type
Degree Program
School
Patent number
Funder(s)
Grant identifier(s)
Rights Statement
Rights Statement
© The Author(s) 2008. For information about this journal please refer to the journal's website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See http://creativecommons.org/licenses/by/2.0/uk/legalcode
Item Access Status
Note
Access the data
Related item(s)
Subject
Chemical Sciences
Persistent link to this record
Citation
Collections