Synthesis of the Sialic Acid (-)-KDN and Certain Epimers from (-)-3-Dehydroshikimic Acid or (-)-Quinic Acid
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G. Banwell, Martin
L. Hungerford, Natasha
A. Jolliffe, Katrina
L. Hungerford, Natasha
A. Jolliffe, Katrina
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Date
2004
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Abstract
(-)-3-Dehydroshikimic acid (3-DHS, 4), a C(7)-building block now available in large quantity from corn syrup, has been converted into the sialic acid (-)-KDN (3) as well as its C-7- and C-8-epimers. (-)-Quinic acid can be used for the same purpose.
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Organic Letters
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6
Issue
16
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Organic Chemical Synthesis
Chemical Sciences