The 1:1 proton-transfer compound of benzylamine with 3,5-dinitrosalicylic acid
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Wermuth, UD
Healy, PC
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Abstract
The crystal structure of the proton-transfer compound from the reaction of 3,5-dinitrosalicylic acid (DNSA) with benzylamine (BA), viz. benzylammonium 3,5-dinitrosalicylate, C7H10N+烷H3N2O7-, shows a hydrogen-bonded polymer in which the protonated primary amine group of benzylamine gives a total of six inter-species interactions with O atoms of the DNSA anions. In addition, there are unusual centrosymmetric interactions between the carboxylate groups of the DNSA anions.
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ACTA Crystallographica Section E - Structure Reports Online
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58
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© The Author(s) 2002 For information about this journal please refer to the journal's website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See http://creativecommons.org/licenses/by/2.0/uk/legalcode
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Chemical sciences