Following dynamic nuclear wave packets in N2,O2, and CO with few-cycle infrared pulses
File version
Author(s)
Magrakvelidze, M
Bocharova, IA
Ray, D
Cao, W
Znakovskaya, I
Li, H
Wang, Z
Laurent, G
Thumm, U
Kling, MF
Litvinyuk, IV
Ben-Itzhak, I
Cocke, CL
Griffith University Author(s)
Primary Supervisor
Other Supervisors
Editor(s)
Date
Size
File type(s)
Location
License
Abstract
We study the evolution of nuclear wave packets launched in molecular nitrogen, oxygen, and carbon monoxide by intense 8-fs infrared pulses. We use velocity map imaging to measure the momentum of the ion fragments when these wave packets are interrogated by a second such pulse after a variable time delay. Both quasibound and dissociative wave packets are observed. For the former, measurements of bound-state oscillations are used to identify the participating states and, in some cases, extract properties of the relevant potential-energy surfaces. Vibrational structure is resolved in both energy and oscillation frequencies for the cations of oxygen and carbon monoxide, displaying the same quantum wave-packet motion in both energy and time domains. In addition, vibrational structure is seen in the dication of carbon monoxide in a situation where the energy resolution by itself is inadequate to resolve the structure.
Journal Title
Physical Review A
Conference Title
Book Title
Edition
Volume
84
Issue
4
Thesis Type
Degree Program
School
Publisher link
Patent number
Funder(s)
Grant identifier(s)
Rights Statement
Rights Statement
Item Access Status
Note
Access the data
Related item(s)
Subject
Mathematical sciences
Physical sciences
Atomic and molecular physics
Chemical sciences