Thermodynamics from first principles: Correlations and nonextensivity
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Gould, Tim
Cavalcanti, EG
Vaccaro, JA
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Abstract
The standard formulation of thermostatistics, being based on the Boltzmann-Gibbs distribution and logarithmic Shannon entropy, describes idealized uncorrelated systems with extensive energies and short-range interactions. In this Rapid Communication, we use the fundamental principles of ergodicity (via Liouville's theorem), the self-similarity of correlations, and the existence of the thermodynamic limit to derive generalized forms of the equilibrium distribution for long-range-interacting systems. Significantly, our formalism provides a justification for the well-studied nonextensive thermostatistics characterized by the Tsallis distribution, which it includes as a special case. We also give the complementary maximum entropy derivation of the same distributions by constrained maximization of the Gibbs-Shannon entropy. The consistency between the ergodic and maximum entropy approaches clarifies the use of the latter in the study of correlations and nonextensive thermodynamics.
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Physical Review E
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101
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6
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© 2020 American Physical Society. This is the author-manuscript version of this paper. Reproduced in accordance with the copyright policy of the publisher. Please refer to the journal's website for access to the definitive, published version.
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Mathematical sciences
Physical sciences
Classical physics
Thermodynamics and statistical physics
Science & Technology
Physics, Fluids & Plasmas
Physics, Mathematical
Physics
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Saadatmand, SN; Gould, T; Cavalcanti, EG; Vaccaro, JA, Thermodynamics from first principles: Correlations and nonextensivity, Physical Review E, 101(6), 2020