Regioselective green anomeric deacetylation catalyzed by lanthanide triflates
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Author(s)
Tran, Anh Tuan
Deydier, Sophie
Bonnaffe, David
Narvor, Christine
Deydier, Sophie
Bonnaffe, David
Narvor, Christine
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2008
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Abstract
Lanthanide triflates, especially Nd(OTf)3, efficiently catalyze the regioselective transesterification of anomeric acetates. This method offers an efficient solution for the otherwise difficult removal of methyl uronates anomeric acetates as well as a green alternative to published protocols since the lanthanide catalysts are non-toxic and may be easily recycled and reused.
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Tetrahedron Letters
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49
Issue
13
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Organic Green Chemistry
Medicinal and Biomolecular Chemistry
Organic Chemistry