A new pyrene cored small organic molecule with a flexible alkyl spacer: a potential solution processable blue emitter with bright photoluminescence
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Wong, FL
Shinde, Durgaprasad
Lee, CS
Roy, VAL
Manzhos, Sergei
Feron, K
Chang, Samuel
Katoh, Ryuzi
Sonar, Prashant
Wadgaonkar, Prakash P
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Abstract
A new pyrene cored small organic molecule viz. 1,3,6,8-tetrakis(4-((5-(9H-carbazol-9-yl)pentyl)oxy)phenyl)pyrene (PY-II) was designed and synthesized. The carbazole moiety with an alkyl spacer was introduced at 1, 3, 6 and 8 positions of the pyrene core to improve the charge transport properties and solution processability. PY-II exhibited excellent solubility in common organic solvents and high thermal stability up to 345 °C. The photoluminescence quantum yield (PLQY) of PY-II in solution was found to be 0.9 with bright blue emission near 450 nm which is just appropriate for the human eye. The solution processed non-doped OLED device fabricated using PY-II as an emissive layer afforded a pure blue emission with CIE coordinates of 0.16 and 0.16, a power efficiency of 0.17 lm W−1, a maximum current efficiency of 0.41 cd A−1 and a maximum brightness of 202 cd m−2.
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New Journal of Chemistry
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41
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19
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© 2017 Royal Society of Chemistry. This is the author-manuscript version of this paper. Reproduced in accordance with the copyright policy of the publisher. Please refer to the journal website for access to the definitive, published version.
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Chemical sciences
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Physical Sciences
Chemistry, Multidisciplinary
Chemistry
RED PHOSPHORESCENT OLEDS
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Valsange, NG; Wong, FL; Shinde, D; Lee, CS; Roy, VAL; Manzhos, S; Feron, K; Chang, S; Katoh, R; Sonar, P; Wadgaonkar, PP, A new pyrene cored small organic molecule with a flexible alkyl spacer: a potential solution processable blue emitter with bright photoluminescence, New Journal of Chemistry, 2017, 41 (19), pp. 11383-11390