A new pyrene cored small organic molecule with a flexible alkyl spacer: a potential solution processable blue emitter with bright photoluminescence

Loading...
Thumbnail Image
File version

Accepted Manuscript (AM)

Author(s)
Valsange, Nitin G
Wong, FL
Shinde, Durgaprasad
Lee, CS
Roy, VAL
Manzhos, Sergei
Feron, K
Chang, Samuel
Katoh, Ryuzi
Sonar, Prashant
Wadgaonkar, Prakash P
Griffith University Author(s)
Primary Supervisor
Other Supervisors
Editor(s)
Date
2017
Size
File type(s)
Location
License
Abstract

A new pyrene cored small organic molecule viz. 1,3,6,8-tetrakis(4-((5-(9H-carbazol-9-yl)pentyl)oxy)phenyl)pyrene (PY-II) was designed and synthesized. The carbazole moiety with an alkyl spacer was introduced at 1, 3, 6 and 8 positions of the pyrene core to improve the charge transport properties and solution processability. PY-II exhibited excellent solubility in common organic solvents and high thermal stability up to 345 °C. The photoluminescence quantum yield (PLQY) of PY-II in solution was found to be 0.9 with bright blue emission near 450 nm which is just appropriate for the human eye. The solution processed non-doped OLED device fabricated using PY-II as an emissive layer afforded a pure blue emission with CIE coordinates of 0.16 and 0.16, a power efficiency of 0.17 lm W−1, a maximum current efficiency of 0.41 cd A−1 and a maximum brightness of 202 cd m−2.

Journal Title

New Journal of Chemistry

Conference Title
Book Title
Edition
Volume

41

Issue

19

Thesis Type
Degree Program
School
Publisher link
Patent number
Funder(s)
Grant identifier(s)
Rights Statement
Rights Statement

© 2017 Royal Society of Chemistry. This is the author-manuscript version of this paper. Reproduced in accordance with the copyright policy of the publisher. Please refer to the journal website for access to the definitive, published version.

Item Access Status
Note
Access the data
Related item(s)
Subject

Chemical sciences

Science & Technology

Physical Sciences

Chemistry, Multidisciplinary

Chemistry

RED PHOSPHORESCENT OLEDS

Persistent link to this record
Citation

Valsange, NG; Wong, FL; Shinde, D; Lee, CS; Roy, VAL; Manzhos, S; Feron, K; Chang, S; Katoh, R; Sonar, P; Wadgaonkar, PP, A new pyrene cored small organic molecule with a flexible alkyl spacer: a potential solution processable blue emitter with bright photoluminescence, New Journal of Chemistry, 2017, 41 (19), pp. 11383-11390

Collections