Polymeric anhydrous sodium 2-aminobenzensulfonate
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Wermuth, UD
Young, DJ
Healy, PC
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Abstract
The crystal structure of anhydrous sodium 2-aminobenzenesulfonate, [Na(C6H6NO3S)]n, reveals the presence of a two-dimensional sandwich polymer structure based on a distorted octahedral six-coordinate NaO5N repeating unit. O-Donor atoms are from five different sulfonate groups [Na-O = 2.294 (3)-2.532 (3) ŝ and an amine nitrogen [Na-N = 2.572 (3) ŝ, completing a six-membered chelate ring including Na. Hydrogen bonds also stabilize the core structure. The outer layers of the sandwich comprise the unassociated benzene rings.
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ACTA Crystallographica Section E - Structure Reports Online
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E60
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6
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© The Author(s) 2004. For information about this journal please refer to the journal's website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See http://creativecommons.org/licenses/by/2.0/uk/legalcode
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Chemical sciences
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