Optical Modeling-Assisted Characterization of Polymer:Fullerene Photodiodes

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Jo, Jun Hyung
Chun, Yong-Sik
Kim, Iigu
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2014
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Abstract

In this paper, the practical viability of an organic bulk heterojunction (BHJ)-based photodiode is studied, including the analysis of dark current density ( Jd in hboxA/cm2), external quantum efficiency (EQE in percent), responsivity (R in A/W), noise-equivalent power (in hboxW/Hz1/2), and specific detectivity (Jones in hboxcmHz1/2/hboxW). The dark current was minimized down to 90 hboxpA/cm2 in rmP3rmHT:rmPC60hboxBM BHJ photodiodes by increasing the thickness, whereas the EQE maintained high values. The measured noise current was 2.20times10−13, 1.13times10−13, and 1.94times10−14hboxA/Hz1/2 for 45-, 55-, and 65-nm BHJ photodiodes, respectively. With those values, the calculated detectivity obtained, given light of a 550 nm wavelength, was 2.55times1011, 5.93times1011, and 4.16times1012 Jones, respectively. The results demonstrated a performance of polymer:fullerence photodiode near equivalent to that of Si-based photodiodes.

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IEEE Photonics Journal

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6

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4

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Atomic, molecular and optical physics

Optical properties of materials

Communications engineering

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