A redox-active 2D covalent organic framework with pyridine moieties capable of faradaic energy storage
File version
Author(s)
Ghazi, Zahid Ali
Liang, Bin
Khan, Niaz Ali
Iqbal, Azhar
Li, Lianshan
Tang, Zhiyong
Griffith University Author(s)
Primary Supervisor
Other Supervisors
Editor(s)
Date
Size
File type(s)
Location
License
Abstract
Covalent organic frameworks (COFs) are a novel class of porous crystalline organic materials assembled from molecular building blocks. Due to their high surface area and ability to precisely control electro-active groups in their pores, COFs have emerged as an ideal candidate for energy storage devices. Here we present a two dimensional (2D) COF with redox active pyridine units that exhibit reversible electrochemical processes. When used as an electrode in supercapacitors, this redox COF shows faradaic behavior and excellent chemical stability even after 6000 charge–discharge cycles. This strategy may shed light on designing new redox active COF based faradaic supercapacitors and other electrochemical devices.
Journal Title
Journal of Materials Chemistry A
Conference Title
Book Title
Edition
Volume
4
Issue
42
Thesis Type
Degree Program
School
Publisher link
Patent number
Funder(s)
Grant identifier(s)
Rights Statement
Rights Statement
Item Access Status
Note
Access the data
Related item(s)
Subject
Macromolecular and materials chemistry
Macromolecular and materials chemistry not elsewhere classified
Materials engineering
Other engineering