The First Aminimide Synthesis from Benzoyl Azide and Pyridine

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Capuano, Ben
T. Crosby, Ian
J. Lloyd, Edward
Neve, Juliette
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2007
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Abstract

Irradiation of benzoyl azide 1 at 254 nm in the presence of some amines produces aminimides: in the presence of pyridine the aminimide 13 can be isolated in 41% yield; in the presence of N,N-dimethylaniline a CH insertion product 7 is obtained via an intermediate aminimide 12. This is the first reported synthesis of aminimides from a benzoyl azide.

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Australian Journal of Chemistry

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60

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3

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Chemical Sciences

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