Syntheses, structures and luminescence properties of three metal–organic frameworks based on 5-(4-(2H-tetrazol-5-yl)phenoxy)isophthalic acid

No Thumbnail Available
File version
Author(s)
He, Hongming
Sun, Fuxing
Su, Hongmin
Jia, Jiangtao
Li, Qin
Zhu, Guangshan
Griffith University Author(s)
Primary Supervisor
Other Supervisors
Editor(s)
Date
2014
Size
File type(s)
Location
License
Abstract

Three metal–organic frameworks (MOFs), namely [Zn2(TPIA)(OH)(H2O)]·H2O (JUC-114), [Cd2(TPIA)(OH)(H2O)2]·H2O (JUC-115), and [Co2(TPIA)(OH)(H2O)2]·H2O (JUC-116) (JUC = Jilin University China), based on a new ligand, 5-(4-(2H-tetrazol-5-yl)phenoxy)isophthalic acid (H3TPIA), were synthesized under hydrothermal conditions and characterized by single crystal X-ray diffraction, elemental analysis, IR spectroscopy, TGA analysis and powder X-ray diffraction. JUC-114, JUC-115 and JUC-116 all possess 3D frameworks with (4,8)-connected fluorite (flu) topology based on similar tetranuclear metal centers as secondary building unit (SBU). Furthermore, the luminescence of the ligand H3TPIA and compounds was measured at room temperature.

Journal Title

CrystEngComm

Conference Title
Book Title
Edition
Volume

16

Issue
Thesis Type
Degree Program
School
Publisher link
Patent number
Funder(s)
Grant identifier(s)
Rights Statement
Rights Statement
Item Access Status
Note
Access the data
Related item(s)
Subject

Inorganic chemistry

Inorganic chemistry not elsewhere classified

Physical chemistry

Materials engineering

Persistent link to this record
Citation
Collections