Correction to Catalyst-Controlled Stereoselective Synthesis Secures the Structure of the Antimalarial Isocyanoterpene Pustulosaisonitrile-1

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White, AM
Dao, K
Vrubliauskas, D
Konst, ZA
Pierens, GK
Mandi, A
Andrews, KT
Skinner-Adams, TS
Clarke, ME
Narbutas, PT
Sim, DC-M
Cheney, KL
Kurtan, T
Garson, MJ
Vanderwal, CD
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2018
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Abstract

© 2018 American Chemical Society. In the Graphical Abstract, Figure 5, and Scheme 1, the configurations at C14 in several epoxide intermediates were drawn incorrectly. Ultimately, these errors have no consequence for the conclusion of the published work; that is, the relative and absolute configurations of pustulosaisonitrile-1 that were arrived at by our work stand as shown throughout the paper. All of the characterization data for all new compounds remains correct. The corrected graphics are provided here, as are the changes for the text. The appropriate corrections have been made to the Supporting Information. Text corrections: Page 13317, second column, second line: "⋯the (S)-isomer of farnesyl epoxide" should read "⋯the (R)-isomer of farnesyl epoxide". Page 13317, second column, ninth line: "The (S)-configured epoxide⋯" should read "The (R)-configured epoxide⋯". Page 13317, caption for Figure 5: "⋯from (S)-farnesyl epoxide" should read "⋯from (R)-farnesyl epoxide". (Figure Presented).

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Journal of Organic Chemistry
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83
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16
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Medicinal and biomolecular chemistry
Organic chemistry
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White, AM; Dao, K; Vrubliauskas, D; Konst, ZA; Pierens, GK; Mandi, A; Andrews, KT; Skinner-Adams, TS; Clarke, ME; Narbutas, PT; Sim, DC-M; Cheney, KL; Kurtan, T; Garson, MJ; Vanderwal, CD, Correction to Catalyst-Controlled Stereoselective Synthesis Secures the Structure of the Antimalarial Isocyanoterpene Pustulosaisonitrile-1, Journal of Organic Chemistry, 2018, 83 (16), pp. 9571-9572
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