A binuclear iminodiacetato-copper(II) complex with the N,N'-bis(pyridine-4-ylmethylene)hydrazine ligand as spacer

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Kundu, Nabanita
Chatterjee, Pabitra Baran
Chaudhury, Muktimony
Tiekink, Edward
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2005
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Abstract

The centrosymmetric title compound, -N,N'-bis(pyridin-4-ylmethylene)hydrazine-bis[diaqua(iminodiacetato)copper(II)], [Cu2(C4H5NO4)2(C12H10N4)(H2O)4], features a trans-N2O4 donor set that defines a heavily distorted octahedral geometry. Coordination is provided by a tridentate iminodiacetate (ida) dianion, one end of a bidentate bridging N,N'-bis(pyridin-4-ylmethylene)hydrazine ligand, which is disposed about a centre of inversion, and two water molecules. Extensive hydrogen bonding leads to a cohesive crystal structure.

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Acta crystallographica. Section E, Structure reports online

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E61

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© The Author(s) 2005. For information about this journal please refer to the journal’s website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See http://creativecommons.org/licenses/by/2.0/uk/legalcode

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Chemical Sciences

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