Electron impact excitation of N3+ using the B-spline R-matrix method: importance of the target structure description and the size of the close-coupling expansion

Loading...
Thumbnail Image
File version

Accepted Manuscript (AM)

Author(s)
Fernandez-Menchero, L
Zatsarinny, O
Bartschat, K
Griffith University Author(s)
Primary Supervisor
Other Supervisors
Editor(s)
Date
2017
Size
File type(s)
Location
License
Abstract

There are major discrepancies between recent intermediate coupling frame transformation (ICFT) and Dirac atomic R-matrix code (DARC) calculations (Fernández-Menchero et al 2014 Astron. Astrophys. 566 A104; Aggarwal et al 2016 Mon. Not. R. Astron. Soc. 461 3997) regarding electron-impact excitation rates for transitions in several Be-like ions, as well as claims that the DARC calculations are much more accurate and the ICFT results might even be wrong. To identify possible reasons for these discrepancies and to estimate the accuracy of the various results, we carried out independent B-spline R-matrix calculations for electron-impact excitation of the Be-like ion N3+. Our close-coupling (CC) expansions contain the same target states (238 levels overall) as the previous ICFT and DARC calculations, but the representation of the target wave functions is completely different. We find close agreement among all calculations for the strong transitions between low-lying states, whereas there remain serious discrepancies for the weak transitions as well as for transitions to highly excited states. The differences in the final results for the collision strengths are mainly due to differences in the structure description, specifically the inclusion of correlation effects, rather than the treatment of relativistic effects or problems with the validity of the three methods to describe the collision. Hence there is no indication that one approach is superior to another, until the convergence of both the target configuration and the CC expansions have been fully established.

Journal Title

Journal of Physics B: Atomic, Molecular and Optical Physics

Conference Title
Book Title
Edition
Volume

50

Issue

6

Thesis Type
Degree Program
School
Publisher link
Patent number
Funder(s)
Grant identifier(s)
Rights Statement
Rights Statement

© 2017 Institute of Physics Publishing. This is the author-manuscript version of this paper. Reproduced in accordance with the copyright policy of the publisher. Please refer to the journal's website for access to the definitive, published version.

Item Access Status
Note
Access the data
Related item(s)
Subject

Atomic, molecular and optical physics

Theoretical and computational chemistry

Science & Technology

Physical Sciences

Optics

Physics, Atomic, Molecular & Chemical

Physics

Persistent link to this record
Citation

Fernandez-Menchero, L; Zatsarinny, O; Bartschat, K, Electron impact excitation of N3+ using the B-spline R-matrix method: importance of the target structure description and the size of the close-coupling expansion, Journal of Physics B: Atomic, Molecular and Optical Physics, 2017, 50 (6)

Collections