Metal ligand bond contraction and possible spin-orbit induced Jahn-Teller distortion in the iron(III) dialkyldithiocarbamate 'crossover' system

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HEALY, PC
WHITE, AH
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1971
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Abstract

Comparison of the crystal structure of high- and low-spin iron(III) dialkyldithiocarbamate complexes, [Fe(CS2玒2)3], reveals (a) the predicted difference (0籠ũ in metal-sulphur bond length and (b) an unusual distortion from D3 to C3 symmetry in the low-spin complex, attributed to spin-orbit interactions in the ground state.

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Chemical Communications
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1971
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22
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© 1971 Royal Society of Chemistry. Please refer to the journal link for access to the definitive, published version.
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Chemical Sciences
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