A chemoenzymatic synthesis of the styryllactone (+)-goniodiol from naphthalene.
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Banwell, MG
Coster, MJ
Karunaratne, OP
Smith, JA
Coster, MJ
Karunaratne, OP
Smith, JA
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2002
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Abstract
The enantiomerically pure cis-1,2-diol I, which is obtained by microbial oxidn. of naphthalene, has been converted, via a sequence of reactions including oxidative C-C bond cleavage, decarbonylation and ring-closing metathesis steps, into the natural product (+)-goniodiol (II).
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Journal of the Chemical Society, Perkin Transactions 1
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2002
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Medicinal and biomolecular chemistry
Organic chemistry