Conformational isomerism in 3-(Z)-isobutylidene-1-acetylpiperazine-2,5-dione
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McCleary, MA
Healy, PC
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Abstract
The title compound, C10H14N2O3, (I), is a key intermediate in the synthesis of the cyclic dehydropeptide albonoursin, which has been found to exhibit useful biological and pharmacological properties. It crystallizes with two molecules in the asymmetric unit with different conformational structures. The methylpropylidene side chain is found to be in the Z configuration about the C=C double bond for both molecules.
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ACTA Crystallographica Section E - Structure Reports Online
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59
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© The Author(s) 2003. For information about this journal please refer to the journal's website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See http://creativecommons.org/licenses/by/2.0/uk/legalcode
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Chemical sciences