Structural characterization of the reaction products of vanadium(II) and endrin as the two isomers of 1,8,exo-9,10,11-pentachloropentacyclo[6.2.1.13,6.O2,7O4,10]dodecan-5-one
File version
Author(s)
HEALY, PC
PATCH, GJ
SKELTON, BW
WHITE, AH
Griffith University Author(s)
Primary Supervisor
Other Supervisors
Editor(s)
Date
Size
File type(s)
Location
License
Abstract
Two dechlorinated products (B) and (D), formed in the reaction between endrin (C12H8Cl6O) and vanadium(II) for the purpose of confirmation of identity, are shown by single-crystal X-ray structure determination to be isomers of the title compound, C12H9Cl5O. Crystals of both are monoclinic, P21/c. For isomer (B), a 7.432(8), b 12.76(1), c 14.55(2) Š, ߠ108.32(9)ꬠZ=4; R was 0.038 for 2594 observed reflections. For isomer (D), a 9.037(4), b 12.004(4), c 14.436(6) Š, ߠ124.91(2)ଠZ= 4; R was 0.041 for 1826 reflections. The geometries of the two isomers are compared.
Journal Title
Australian Journal of Chemistry
Conference Title
Book Title
Edition
Volume
42
Issue
Thesis Type
Degree Program
School
Publisher link
Patent number
Funder(s)
Grant identifier(s)
Rights Statement
Rights Statement
Item Access Status
Note
Access the data
Related item(s)
Subject
Chemical sciences