Scalable Fabrication of Black Phosphorous Films for Infrared Photodetector Arrays

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Corletto, A
Myagmarsereejid, P
Wang, S
Yan, W
Balendhran, S
Liu, H
Zhong, YL
Crozier, KB
Batmunkh, M
Bullock, J
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2024
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Abstract

Bulk black phosphorous (bP) exhibits excellent infrared (IR) optoelectronic properties, but most reported bP IR photodetectors are fabricated from single exfoliated flakes with lateral sizes of < 100 µm. Here, scalable thin films of bP suitable for IR photodetector arrays are realized through a tailored solution-deposition method. The properties of the bP film and their protective capping layers are optimized to fabricate bP IR photoconductors exhibiting specific detectivities up to 4.0 × 108 cm Hz1/2 W−1 with fast 30/60 µs rise/fall times under λ = 2.2 µm illumination. The scalability of the bP thin film fabrication is demonstrated by fabricating a linear array of 25 bP photodetectors and obtaining 25 × 25 pixel IR images at ≈203 ppi with good spatial fidelity. This research demonstrates a commercially viable method of fabricating scalable bP thin films for optoelectronic devices including room temperature-operable IR photodetector arrays.

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Advanced Science

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© 2024 The Author(s). Advanced Science published by Wiley-VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.

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This publication has been entered in Griffith Research Online as an advance online version.

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Photonics, optoelectronics and optical communications

Nanotechnology

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Corletto, A; Myagmarsereejid, P; Wang, S; Yan, W; Balendhran, S; Liu, H; Zhong, YL; Crozier, KB; Batmunkh, M; Bullock, J, Scalable Fabrication of Black Phosphorous Films for Infrared Photodetector Arrays, Advanced Science, 2024, pp. 2403182

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